Anthropogenic influence of trace metals in sediments of the Al-Qilt catchment,West Bank,Palestine: 1. Contamination factor and bonding forms     

Sobhi Samhan  Kurt Friese  Wolf von Tümpling  Herbert Pöllmann  Heinz Hoetzl  Marwan Ghanem 《Environmental Earth Sciences》2014,71(4):1533-1539

Al-Qilt catchment, located east of both the Ramallah and Jerusalem districts is strongly influenced by waste waters discharged from Israeli settlements and Palestinian urban centers. In this research, our aim was to verify the chemical status of the surface sediments from the Al-Qilt catchment during 2008/2009. For this purpose, 36 surface sediment samples were collected and analyzed with ICP/MS within the fraction of below 63 μm. The extent of contamination of trace metals from Al-Qilt sediments sites were measured by evaluating the contamination factors (CF) from digestion by aqua regia and additionally by sequential extraction steps using the BCR-method. On the basis of the calculated CF, sediments appear particularly contaminated with Zn, Cu, Ag, Sn, Cd, Hg, Bi, and B. Three regions, Wadi Sweanit, Ras Al-Qilt, and Qalandiah have been identified as critical points of contamination. Trace metal inputs to the Al-Qilt catchment need to be kept under strict control in the future since Ras Al-Qilt is considered as one of the important springs in the area and is used for domestic purposes. Moreover, it will be susceptible to pollution if no action is taken to decrease the pollution at the upstream of Al-Qilt.  相似文献   

A search for amino acids and nucleobases in the Martian meteorite Roberts Massif 04262 using liquid chromatography‐mass spectrometry     

Michael P. Callahan  Aaron S. Burton  Jamie E. Elsila  Eleni M. Baker  Karen E. Smith  Daniel P. Glavin  Jason P. Dworkin 《Meteoritics & planetary science》2013,48(5):786-795

The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.  相似文献   

Composition and petrology of HED polymict breccias: The regolith of (4) Vesta     

David W. Mittlefehldt  Jason S. Herrin  Julie E. Quinn  Stanley A. Mertzman  Julia A. Cartwright  Karen R. Mertzman  Zhan X. Peng 《Meteoritics & planetary science》2013,48(11):2105-2134

We have done petrologic and compositional studies on a suite of polymict eucrites and howardites to better understand regolith processes on their parent asteroid, which we accept is (4) Vesta. Taking into account noble gas results from companion studies, we interpret five howardites to represent breccias assembled from the true regolith: Elephant Moraine (EET) 87513, Grosvenor Mountains (GRO) 95535, GRO 95602, Lewis Cliff (LEW) 85313, and Meteorite Hills (MET) 00423. We suggest that EET 87503 is paired with EET 87513, and thus is also regolithic. Pecora Escarpment (PCA) 02066 is dominated by melt‐matrix clasts, which may have been formed from true regolith by impact melting. These meteorites display a range in eucrite:diogenite mixing ratio from 55:45 to 76:24. There is no correlation between degree of regolith character and Ni content. The Ni contents of howardite, eucrite, and diogenites (HEDs) are mostly controlled by the distribution of coarse chondritic clasts and metal grains, which in some cases resulted from individual, low‐velocity accretion events, rather than extensive regolith gardening. Trace element compositions indicate that the mafic component of HED polymict breccias is mostly basalt similar to main‐group eucrites; Stannern‐trend basaltic debris is less common. Pyroxene compositions show that some trace element‐rich howardites contain abundant debris from evolved basalts, and that cumulate gabbro debris is present in some breccias. The scale of heterogeneity varies considerably; regolithic howardite EET 87513 is more homogeneous than fragmental howardite Queen Alexandra Range (QUE) 97001. Individual samples of a given howardite can have different compositions even at roughly 5 g masses, indicating that obtaining representative meteorite compositions requires multiple or large samples.  相似文献   

A high-resolution infrared spectral survey of Comet C/1999 H1 Lee     

Neil Dello Russo  Michael J. Mumma  Karen Magee-Sauer  Boncho P. Bonev  I.S. McLean 《Icarus》2006,184(1):255-276

We obtained high-resolution (λ/Δλ∼25,000) spectra of Comet C/1999 H1 (Lee) on UT 1999 August 19.6 and 21.6 using the cross-dispersed Near InfraRed SPECtrometer (NIRSPEC) at the Keck Observatory atop Mauna Kea, HI. Here we present spectra of Comet Lee between 2.874 and 3.701 μm (3479-2702 cm⁻¹) representing the most complete high-resolution infrared survey of a comet to date in this wavelength region. Using published line lists and laboratory spectra we have identified 444 of the 545 distinct emission features present in these spectra. We have tabulated the rest frequencies, assignments, relative intensities, and signal-to-noise ratios of all detected emissions. In addition to gaining insights into the chemistry of Comet Lee, this survey provides a valuable tool for planning future high-resolution infrared observations of comets and other astronomical targets, and for retrospective comparison to existing high-resolution infrared datasets.  相似文献   

I S L A An Astronomical World Space Observatory for The First Century of the 3 rd Millenium     

G.F.O. von Appen-Schnur  T. Luks 《Astrophysics and Space Science》1997,258(1-2):301-328

ISLA will be an astronomical observatory, operating at the upper limit of our planet Earth atmosphere, offering space like observing conditions in most aspects. ISLA can be maintained easily, modified easily if necessary, always kept at the state of the art and operated for very extended periods without polluting the stratosphere. ISLA is ideally suited to become the first world space observatory as the observing conditions are very much space-like – diffraction limited angular resolution, very low ambient temperature, remote control – however ISLA is easily accessible, telescopes and instruments can be continuously improved and ISLA's costs corresponds only to those of ground-based modern astronomical installations like the ESO-VLT-, KECK- and GEMINI-observatories. The cost of observing and experimenting on ISLA will be orders of magnitudes lower than those of building and operating any space telescope, allowing the astronomers of developing nations to participate in the ISLA observatory within their limited financial possibilities as competent and full partners. ISLA's 4-m and 2-m telescopes will operate diffraction limited from 0.3 μm in the optical, over the infrared, far-infrared to the sub-mm spectral range. ISLA's individual telescopes will permit imaging with 20 milli-arcsec spatial resolution in the optical, 5 times better than the Hubble Space Telescope. ISLA's telescopes can be combined to form an interferometer with a maximum baseline of 250 m with nearly complete coverage of the u,v plane. Interferometric resolution will be of the order of 20 micro-arcsec for the optical. ISLA will thus offer spatial resolution comparable or better than the intercontinental VLBI radio interferometers. ISLA's telescope efficiency will be many orders of magnitude better than comparable ground-based telescopes. The light collecting power of ISLA's interferometric telescopes will be orders of magnitudes greater than the future space interferometers under discussion. ISLA, being an aviation project and not a space project, can be realised in the typical time scale for the development of aviation: about 5 years. ISLA's cost for the whole observatory, including its movable ground station etc. will be of the order of a typical medium size ESA space mission. ISLA's lifetime will be in excess of many decades, as it can easily be maintained, modernised, repaired and improved. ISLA will become the origin of a new astronomical international organisation with worldwide participation. ISLA's telescopes will be of the greatest importance to all astronomical fields, as it will permit to study much fainter, much more distant objects with microscopic spatial resolution in wavelength regions inaccessible from ground. ISLA's many telescopes permit easily simultaneous observations at many wavelengths for rapidly varying objects, from continuously monitoring the surfaces of the planets in our solar system, surfaces of close-by stars, nuclei of galaxies to QSO's. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Star Formation in Violent and Normal Evolutionary Phases     

Uta Fritze – von Alvensleben 《Astrophysics and Space Science》2002,281(1-2):379-382

Mergers of massive gas-rich galaxies trigger violent starbursts that - over timescales of > 100 Myr and regions > 10 kpc - form massive and compact star clusters comparable in mass and radii to Galactic globular clusters. The star formation efficiency is higher by 1–2 orders of magnitude in these bursts than in undisturbed spirals, irregulars or even BCDs. We ask the question if star formation in these extreme regimes is just a scaled-up version of the normal star formation mode of if the formation of globular clusters reveals fundamentally different conditions. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Response of surface water chemistry to reduced levels of acid precipitation: comparison of trends in two regions of New York,USA     

Douglas A. Burns  Michael R. McHale  Charles T. Driscoll  Karen M. Roy 《水文研究》2006,20(7):1611-1627

In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984–2001 and 1992–2001) and surface water chemistry (1992–2001) were determined in two of the most acid‐sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO₄^2?), nitrate (NO₃^?), and base cation (C_B) concentrations and increasing pH during 1984–2001, but few significant trends during 1992–2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO₄^2? concentrations at all sites, and decreasing trends in NO₃^?, C_B, and H⁺ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid‐neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO₄^2? trends, but it caused several significant non‐flow‐corrected trends in NO₃^? and ANC to become non‐significant, suggesting that trend results for flow‐sensitive constituents are affected by flow‐related climate variation. SO₄^2? concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation–surface water comparisons, reflecting a strong link between S emissions, precipitation SO₄^2? concentrations, and the processes that affect S cycling within these regions. NO₃^? and H⁺ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation–surface water comparisons, indicating that variation in local‐scale processes driven by factors such as climate are affecting trends in acid–base chemistry in these two regions. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Fluid inclusion evidence for impact‐related hydrothermal fluid and hydrocarbon migration in Creataceous sediments of the ICDP‐Chicxulub drill core Yax‐1     

Volker Lüders  Karen Rickers 《Meteoritics & planetary science》2004,39(7):1187-1197

Fluid inclusions studies in quartz and calcite in samples from the ICDP‐Chicxulub drill core Yaxcopoil‐1 (Yax‐1) have revealed compelling evidence for impact‐induced hydrothermal alteration. Fluid circulation through the melt breccia and the underlying sedimentary rocks was not homogeneous in time and space. The formation of euhedral quartz crystals in vugs hosted by Cretaceous limestones is related to the migration of hot (>200 °C), highly saline, metal‐rich, hydrocarbon‐bearing brines. Hydrocarbons present in some inclusions in quartz are assumed to derive from cracking of pre‐impact organic matter. The center of the crater is assumed to be the source of the hot quartz‐forming brines. Fluid inclusions in abundant newly‐formed calcite indicate lower cyrstallization temperatures (75–100 °C). Calcite crystallization is likely related to a later stage of hydrothermal alteration. Calcite precipitated from saline fluids, most probably from formation water. Carbon and oxygen isotope compositions and REE distributions in calcites and carbonate host rocks suggest that the calcite‐forming fluids have achieved close equilibrium conditions with the Cretaceous limestones. The precipitation of calcite may be related to the convection of local pore fluids, possibly triggered by impact‐induced conductive heating of the sediments.  相似文献   

Boundary layer ion composition at Jupiter during the inbound pass of the Ulysses flyby     

A.B. Galvin  C.M.S. Cohen  F.M. Ipavich  R. von Steiger  J. Woch  U. Mall 《Planetary and Space Science》1993,41(11-12)

During the inbound segment of the Ulysses flyby of Jupiter, there were multiple incursions into the dawnside low-latitude boundary layer, as identified by Bame et al. (Science257, 1539–1542, 1992) using plasma electron data. In the present study, ion composition and spectral measurements provide independent collaborative evidence for the existence of distinct boundary layer regions. Measurements are taken in the energy-per-charge range of 0.6–60 keV/e and involve mass as well as mass-per-charge identification by the Ulysses/SWICS experiment. Ion species of Jovian magnetospheric origin (including O⁺, O²⁺, S²⁺, S³⁺) and sheath origin (including He²⁺ and high charge state CNO) have been directly identified for the first time in the Jovian magnetospheric boundary layer. Protons of probably mixed origin and He⁺ of possibly sheath (ultimately interstellar pickup) origin were also observed in the boundary layer. Sheath-like ions are observed throughout the boundary layer; however, the Jovian ions are depleted or absent for portions of two boundary layer cases studied. Ions of solar wind origin are observed within the outer magnetosphere. and ions of magnetospheric origin are found within the sheath, indicating that transport across the magnetopause boundary can work both ways, at least under some conditions. Although their source cannot be uniquely identified, the proton energy spectrum in the boundary layer suggests a sheath origin for the lower energy protons.  相似文献   

Longitudinal dispersion compensation for the Very Large Telescope Interferometer     

Samuel Lévêque  Bertrand Koehler  Oskar von der Lühe 《Astrophysics and Space Science》1996,239(2):305-314

The Very Large Telescope Interferometer [1,13] will be operated in air which will introduce small optical path fluctuations due to internal turbulence [4,6] and dispersion effects. Both may contribute to fringe contrast decrease. Longitudinal dispersion effects can be corrected by inserting an appropriate glass of variable thickness in one arm of the interferometer [3,5,11,12]. This paper presents a new method applied to VLTI in order to select the optimum glass, according to both the observing wavelength and the spectral bandpath, and to calculate its thickness. Results are presented in terms of improvement on the fringe contrast.  相似文献